Standard Reduction Potential Equation:
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The standard reduction potential equation calculates the potential difference of an electrochemical cell by subtracting the anode potential from the cathode potential. This fundamental equation in electrochemistry helps predict the spontaneity of redox reactions.
The calculator uses the standard reduction potential equation:
Where:
Explanation: The equation represents the difference in reduction potentials between the two half-cells, determining the overall cell voltage.
Details: Calculating cell potential is crucial for understanding battery performance, predicting reaction spontaneity, and designing electrochemical systems.
Tips: Enter standard reduction potentials for both cathode and anode in volts (V). The calculator will compute the cell potential.
Q1: What does a positive Ecell indicate?
A: A positive value indicates a spontaneous reaction under standard conditions.
Q2: How are standard reduction potentials determined?
A: They are measured against a standard hydrogen electrode (SHE) which is assigned 0 V.
Q3: Can this calculator be used for non-standard conditions?
A: No, this calculates standard potential only. For non-standard conditions, use the Nernst equation.
Q4: What's the relationship between Ecell and Gibbs free energy?
A: ΔG° = -nFE° where n is electrons transferred and F is Faraday's constant.
Q5: Why are some reduction potentials negative?
A: Negative values indicate the species is more difficult to reduce than hydrogen.