Cell Potential Equation:
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The standard reduction potential equation calculates the cell potential (Ecell) by subtracting the anode potential from the cathode potential. This value indicates the voltage difference between the two half-cells in an electrochemical cell.
The calculator uses the cell potential equation:
Where:
Explanation: The equation shows that cell potential depends on the difference between the reduction potentials of the two half-reactions.
Details: Cell potential calculations are crucial for predicting the spontaneity of redox reactions, designing batteries, and understanding electrochemical processes.
Tips: Enter standard reduction potentials for both cathode and anode in volts (V). The cathode is where reduction occurs, and the anode is where oxidation occurs.
Q1: What does a positive Ecell value mean?
A: A positive value indicates a spontaneous reaction under standard conditions.
Q2: How do I know which is cathode and which is anode?
A: The cathode has the higher (more positive) reduction potential; the anode has the lower (more negative) reduction potential.
Q3: What are standard conditions?
A: 1M concentrations, 1 atm pressure (for gases), and 25°C (298K) temperature.
Q4: Can I use this for non-standard conditions?
A: No, this calculator is for standard conditions only. For non-standard conditions, use the Nernst equation.
Q5: What units should I use?
A: All potentials should be in volts (V) relative to the standard hydrogen electrode (SHE).