Standard Cell Potential Equation:
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Standard reduction potential (E°) measures the tendency of a chemical species to be reduced. The standard cell potential (E°cell) is the difference between the reduction potentials of the cathode and anode.
The calculator uses the standard cell potential equation:
Where:
Explanation: The equation shows that cell potential depends on the difference between the reduction potentials of the two half-cells.
Details: The standard cell potential predicts whether a redox reaction will occur spontaneously (positive E°cell) and determines the maximum potential difference of an electrochemical cell.
Tips: Enter standard reduction potentials for both half-reactions in volts (V). The cathode is the reduction half-reaction, and the anode is the oxidation half-reaction (use the reduction potential value).
Q1: What does a positive E°cell indicate?
A: A positive value indicates a spontaneous reaction under standard conditions.
Q2: How do I know which is cathode and anode?
A: The cathode is where reduction occurs (higher reduction potential), and the anode is where oxidation occurs (lower reduction potential).
Q3: What are standard conditions?
A: 25°C (298K), 1 atm pressure, and 1M concentration for all solutions.
Q4: Can I use this for non-standard conditions?
A: No, this calculates standard potential only. Use the Nernst equation for non-standard conditions.
Q5: Where can I find standard reduction potentials?
A: Standard reduction potential tables are available in chemistry references and textbooks.